A frictionless piston-cylinder device contains 5 kg of nitrogen at 100 kPa and 2

grislingatb

grislingatb

Answered question

2021-11-18

A frictionless piston-cylinder device contains 5 kg of nitrogen at 100 kPa and 250 K. Nitrogen is now compressed slowly according to the relation PV1.4= constant until it reaches a final temperature of 450 K. Calculate the work input during this process.

Answer & Explanation

Anot1954

Anot1954

Beginner2021-11-19Added 16 answers

W=mR(T2T1)1n =50.2968(450250)11.4kJ =-742kJ Result 
W=742kJ

Andre BalkonE

Andre BalkonE

Skilled2023-06-15Added 110 answers

Step 1:
Given:
The ideal gas law states:
PV=nRT
Where:
P = pressure
V = volume
n = number of moles of gas
R = gas constant
T = temperature
First, let's find the initial volume of the nitrogen gas. Since the piston-cylinder device is frictionless, the volume remains constant throughout the process. We can rearrange the ideal gas law to solve for volume:
V=nRTP
Substituting the given values:
V1=(5kg)·(8.314J/mol·K)·(250K)100kPa=10435.5100=104.36m3
Step 2:
Now, let's find the final volume of the nitrogen gas. Using the given relation PV1.4=constant, we can express volume in terms of pressure:
V=(constantP)11.4
Since the process is slow and quasi-static, the constant remains the same. We can use the initial pressure and volume to find the constant:
PV1.4=constant=P1V11.4=(100kPa)·(104.36m3)1.4
Now, using the final temperature of 450 K, we can find the final pressure:
P2V21.4=P1V11.4
P2=P1V11.4V21.4
Substituting the given values:
P2=(100kPa)·(104.36m3)1.4V21.4
Now, let's find the final volume using the ideal gas law:
V2=nRT2P2
Substituting the given values and solving for V2:
V2=(5kg)·(8.314J/mol·K)·(450K)P2
Step 3:
Now, we can calculate the work done during the process using the equation:
W=V1V2PdV
Since the process is quasi-static, we can replace P with nRTV:
W=V1V2nRTVdV
Integrating the equation and solving for W:
W=nRTln(V2V1)
Substituting the given values and solving for W:
W=(5kg)·(8.314J/mol·K)·450K·ln(V2V1)
Now, we can substitute the expressions for V1, V2, and solve for W.
Jazz Frenia

Jazz Frenia

Skilled2023-06-15Added 106 answers

The ideal gas law states: PV=nRT, where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature.
The work formula for a polytropic process is: W=P2V2P1V11n, where W is the work, P1 and P2 are the initial and final pressures, V1 and V2 are the initial and final volumes, and n is the polytropic index.
Given:
Initial pressure, P1=100kPa
Initial temperature, T1=250K
Final temperature, T2=450K
Polytropic index, n=1.4
Mass of nitrogen, m=5kg
First, we need to find the initial volume using the ideal gas law. Rearranging the equation, we have:
V1=nRT1P1
Substituting the known values, we get:
V1=(m/M)RT1P1
where M is the molar mass of nitrogen.
Next, we find the final volume using the ideal gas law and the given final temperature, T2:
V2=(m/M)RT2P2
Finally, we can calculate the work input using the work formula for a polytropic process:
W=P2V2P1V11n
Substituting the values of P1, P2, V1, V2, and n, we can solve for W.
Note: The molar mass of nitrogen is approximately M=28.0134g/mol.

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