In a study designed to prepare new gasoline-resistant coatings, a polymer chemis

BolkowN

BolkowN

Answered question

2021-10-25

In a study designed to prepare new gasoline-resistant coatings, a polymer chemist dissolves 6.053 g of polyvinyl alcohol) in enough water to make 100.0 mL of solution. At 25C, the osmotic pressure of this solution is 0.272 atm. What is the molar mass of the polymer sample?

Answer & Explanation

tabuordg

tabuordg

Skilled2021-10-26Added 99 answers

Step 1
First we can calculate molarity (M) using the following equation where II stands for osmotic pressure in atm, T stands for temperature in K and R stands for gas constant (R=0.821atm×Lmol×K):
Π=MRT
M=ΠRT
=0.272atm0.0821 atm L mol1K1×298.15K
=0.011mol L1
Now we can use that to calculate the amount of moles (n):
M=nsoluteVsoln
nsolute=M×Vsoln
=0.011 mol L1×100×103L
=1.1×103mol
Finally, we can calculate molar mass of the polymer:
n=mM
M=mn=6.053g1.1×103mol
=5502.73g mol1

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