Why does the added heat have to be reversible in the formula for calculating entropy change?

Bayobusalue

Bayobusalue

Answered question

2022-11-04

Why does the added heat have to be reversible in the formula for calculating entropy change?

Answer & Explanation

luluna81mxmbk

luluna81mxmbk

Beginner2022-11-05Added 17 answers

Although the change in entropy of the system, be it an infinitesimal or finite change, is the same for all paths because entropy is a state function, in order to calculate what the change is you need to do it for a reversible path. Which means if the process is irreversible you need to assume any convenient reversible path and use
d S s y s = δ Q r e v T
to calculate the finite change between two equilibrium states
Δ S s y s = 1 2 δ Q r e v T
Hope this helps.

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