Determine the mass of water formed when 12.5 L NH3

eliaskidszs

eliaskidszs

Answered question

2022-01-12

Determine the mass of water formed when 12.5 L NH3 (at 298 K and 1.50 atm) is reacted with 18.9 L of O2 (at 323 K and 1.1 atm).
4NH3(g)+5O2(g)4NO(g)6H2O(g)

Answer & Explanation

Cheryl King

Cheryl King

Beginner2022-01-13Added 36 answers

Step 1
The balanced reaction taking place is given as,
4NH3(g)+5O2(g)4NO(g)+6H2O(g)
According to ideal gas law,
PV=nRT
where P= pressure in atm
V= volume in L
n= moles
R=gas constant=0.0821 atm.LK.mol
T=temperature in K=TC+273
Step 2
a) For NH3,P=1.50 atm,V=12.5L and T=298K
Hence substituting the values we get,
1.50×12.5=n×0.0821×298
n=moles of NH3 taken=0.7664 mol approx.
b) For O2,P=1.10 atm,V=18.9LandT=323K
Hence substituting the values we get,
1.10×18.9=n×0.0821×323
n=moles of O2 taken=0.784 mol approx.
Step 3
4 NH3(g)+5O2(g)4 NO(g)+6H2O(g)
From the above balanced reaction we can see that 5 moles of O2 is required to react with 4 moles of NH3
Hence moles of O2 required =moles of NH3 taken×54=0.7664×54=0.958 mol
Since moles of O2 taken is less than required. Hence O2 is the limiting reagent and will react completely.
From the above reaction we can see that 5 moles of O2 is reacting to produce 6 moles of H2O.
Hence moles of H2O that can be produced =moles of O2 taken×65=0.784×65=0.9408 mol
Molar mass of H2O=Atomic mass of H×2+Atomic mass of O=1×2+16=18gmol
Hence mass of H2O that can be produced =moles×molar mass=0.9804×18=16.9g approx.
Hence the answer is 16.9 g.
Mary Herrera

Mary Herrera

Beginner2022-01-14Added 37 answers

The mass of water formed is
calculation
Use the ideal gas equation to calculate the moles of NH3 and O2
that is Pv=nRT
where; P= pressure,
V= volume,
n= number of moles,
R=gas constant=0.0821l.atmmol.K
make n the formula of the subject by diving both side by RT
n=PVRT
The moles of NH3
n=1.50atm×12.5L0.0821L.atmmol.k×268K=0.766 moles
The moles of O2
=1.1atm×18.9L0.0821L.atmmol.k×323K=0.784 moles
write the reaction between NH3 and O2
4NH3+5O24 No+6H2O
from equation above 0.766 moles of NH3 reacted to produce
0.766×64=1.149 moles of H2O
0.784moles of O2 reacted to produce0.784×65=0.9408moles of H20
since O2 is totally consumed, O2 is the limiting reagent and therefore the moles of H2O produced =0.9408 moles
mass of H2O=moles×molar mass
from periodic table the molar mass of H2O=(1×2)+16=18gmol
mass=18gmol×0.9408moles=16.93grams

nick1337

nick1337

Expert2023-06-10Added 777 answers

Solution:
First, let's convert the given volumes of NH3 and O2 to the number of moles using the ideal gas law:
For NH3:
PV=nRT
where:
P = pressure of NH3 = 1.50 atm
V = volume of NH3 = 12.5 L
n = number of moles of NH3
R = ideal gas constant = 0.0821 L atm/(mol K)
T = temperature of NH3 = 298 K
Rearranging the equation to solve for n:
n=PVRT
Substituting the given values:
nNH3=(1.50 atm)(12.5 L)(0.0821 L atm/(mol K))(298 K)
Now, let's calculate the number of moles of O2 using the same approach:
For O2:
PV=nRT
where:
P = pressure of O2 = 1.1 atm
V = volume of O2 = 18.9 L
n = number of moles of O2
R = ideal gas constant = 0.0821 L atm/(mol K)
T = temperature of O2 = 323 K
Rearranging the equation to solve for n:
n=PVRT
Substituting the given values:
nO2=(1.1 atm)(18.9 L)(0.0821 L atm/(mol K))(323 K)
Next, let's determine the limiting reactant by comparing the number of moles of NH3 and O2. The balanced equation shows that 4 moles of NH3 react with 5 moles of O2. Therefore, the ratio of moles is 4:5.
We have:
nNH3=(1.50 atm)(12.5 L)(0.0821 L atm/(mol K))(298 K)
nO2=(1.1 atm)(18.9 L)(0.0821 L atm/(mol K))(323 K)
Comparing the moles of NH3 and O2, we find that the moles of NH3 are multiplied by 5/4 to balance the equation.
Now, let's determine the moles of water formed. From the balanced equation, we see that 4 moles of NH3 yield 6 moles of H2O.
Therefore, the number of moles of H2O formed can be calculated as:
nH2O=64×nNH3
Now, we can calculate the mass of H2O formed using the molar mass of water, which is approximately 18.015 g/mol.
mH2O=nH2O×molar mass of H2O
Finally, we substitute the calculated values and solve for the mass of water formed.

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